publication



2010- @@2009-2005 @@review -2005 @@patent -2010
in or before 2004 (PDF file)


2009

"Palladium-catalyzed double cross-coupling reaction of vic-diborylalkenes and -arenes with vic-bromo(bromomethyl)arenes"
Shimizu, Masaki; Tomioka, Yosuke; Nagao, Ikuhiro; Hiyama, Tamejiro
Synlett 2009, 3147-3150.

"Design and synthesis of highly emissive solid fluorophores"
Shimizu, Masaki; Mochida, Kenji; Takeda, Youhei; Asai, Yuiga; Hiyama, Tamejiro
Proceedings of SPIE 2009, 7415.

"Direct Alkenylation and Alkylation of Pyridone Derivatives by Ni/AlMe3 Catalysis"
Nakao, Yoshiaki; Idei, Hiroaki; Kanyiva, Kyalo Stephen; Hiyama, Tamejiro
J. Am. Chem. Soc. 2009, 131, 15996-15997.

"9-Stannafluorenes: 1,4-Dimetal equivalents for aromatic annulation by double cross-coupling"
Nagao, Ikuhiro; Shimizu, Masaki; Hiyama, Tamejiro
Angew. Chem. Int. Ed. 2009, 48, 7573-7576.

"New preparation and synthetic reactions of 3,3,3-trifluoropropynyllithium, -borate and -stannane: facile synthesis of trifluoromethylated allenes, arylacetylenes and enynes"
Shimizu, Masaki; Higashi, Masahiro; Takeda, Youhei; Murai, Masahito; Jiang, Guofang; Asai, Yuiga; Nakao, Yoshiaki; Shirakawa, Eiji; Hiyama, Tamejiro
Future Med. Chem. 2009, 1, 921-945.

Synthesis, crystal structure, and photophysical properties of (1E,3E,5E)-1,3,4,6-tetraarylhexa-1,3,5-trienes: a new class of fluorophores exhibiting aggregation-induced emission"
Shimizu, Masaki; Tatsumi, Hironori; Mochida, Kenji; Shimono, Katsuhiro; Hiyama, Tamejiro
Chem.-An Asian J. (2009), 4, 1289-1297.

"Nickel-Catalyzed Carbocyanation of Alkynes with Allyl Cyanides"
Hirata, Yasuhiro; Yukawa, Tomoya; Kashihara, Natsuko; Nakao, Yoshiaki; Hiyama, Tamejiro
J. Am. Chem. Soc. 2009, 131, 10964-10973.

"Nickel/AlMe2Cl-catalyzed carbocyanation of alkynes using arylacetonitriles"
Yada, Akira; Yukawa, Tomoya; Nakao, Yoshiaki; Hiyama, Tamejiro
Chem. Commun. 2009, 26, 3931-3933.

"Palladium-Catalyzed Intramolecular Coupling of 2-[(2-Pyrrolyl)silyl]aryl Triflates through 1,2-Silicon Migration"
Mochida, Kenji; Shimizu, Masaki; Hiyama, Tamejiro
J. Am. Chem. Soc. 2009, 131, 8350-8351.

"Alkynylcyanation of alkynes and dienes catalyzed by nickel"
Hirata, Yasuhiro; Tanaka, Masaaki; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Tetrahedron 2009, 65, 5037-5050.

"1,4-Bis(alkenyl)-2,5-dipiperidinobenzenes: Minimal Fluorophores Exhibiting Highly Efficient Emission in the Solid State"
Shimizu, Masaki; Takeda, Youhei; Higashi, Masahiro; Hiyama, Tamejiro
Angew. Chem. Int. Ed. 2009, 48, 3653-3656.

"Regioselective alkenylation of imidazoles by nickel/Lewis acid catalysis" Kanyiva, Kyalo Stephen; Loebermann, Florian; Nakao, Yoshiaki; Hiyama, Tamejiro
Tetrahedron Lett. 2009, 50, 3463-3466.

"Cyanoesterification of 1,2-Dienes Catalyzed by Nickel"
Hirata, Yasuhiro; Inui, Tomohiko; Nakao, Yoshiaki; Hiyama, Tamejiro
J. Am. Chem. Soc. 2009, 131, 6624-6631.

"Hydrocarbamoylation of Unsaturated Bonds by Nickel/Lewis-Acid Catalysis"
Nakao, Yoshiaki; Idei, Hiroaki; Kanyiva, Kyalo Stephen; Hiyama, Tamejiro
J. Am. Chem. Soc. 2009, 131, 5070-5071.

"A theoretical study of nickel(0)-catalyzed phenylcyanation of alkynes. Reaction mechanism and regioselectivity"
Ohnishi, Yu-ya; Nakao, Yoshihide; Sato, Hirofumi; Nakao, Yoshiaki; Hiyama, Tamejiro; Sakaki, Shigeyoshi
Organometallics 2009, 28, 2583-2594.

"Transition-Metal-Catalyzed Regioselective Aroyl- and Trifluoroacetylthiolation of Alkynes Using Thioesters. "
Minami, Yasunori; Kuniyasu, Hitoshi; Miyafuji, Kiyoshi; Kambe, Nobuaki
Chem. Commun. 2009, 3080-3082.


2008

"Preparation, structure, and Diels-Alder reaction of phenyl(trifluoromethanesulfonate)(3,3,3-trifluoropropynyl)-3-iodane"
Shimizu, Masaki; Takeda, Youhei; Hiyama, Tamejiro
Chem. Lett. 2008, 37, 1304-1305.

"Modular approach to silicon-bridged biaryls: palladium-catalyzed intramolecular coupling of 2-(arylsilyl)aryl triflates"
Shimizu, Masaki; Mochida, Kenji; Hiyama, Tamejiro
Angew. Chem. Int. Ed. 2008, 47, 9760-9764.

"Nickel-Catalyzed Alkenylation and Alkylation of Fluoroarenes via Activation of C-H Bond over C-F Bond"
Nakao, Yoshiaki; Kashihara, Natsuko; Kanyiva, Kyalo Stephen; Hiyama, Tamejiro
J. Am. Chem. Soc. 2008, 130, 16170-16171.

"Palladium-catalyzed annulation of vic-bis(pinacolatoboryl)alkenes and -phenanthrenes with 2,2'-dibromobiaryls: facile synthesis of functionalized phenanthrenes and dibenzo[g,p]chrysenes"
Shimizu, Masaki; Nagao, Ikuhiro; Tomioka, Yosuke; Hiyama, Tamejiro
Angew. Chem. Int. Ed. 2008, 47, 8096-8099.

"Silicon-bridge effects on photophysical properties of silafluorenes"
Shimizu, Masaki; Tatsumi, Hironori; Mochida, Kenji; Oda, Katsunari; Hiyama, Tamejiro
Chem.-Asian J. 2008, 3, 1238-1247.

"Stereoselective preparation and Cope rearrangement of 2-CF3-cis-2,3-bis(alkenyl)oxiranes: a facile route to 2-CF3-substituted oxacycles"
Shimizu, Masaki; Fujimoto, Takuya; Liu, Xinyu; Takeda, Youhei; Hiyama, Tamejiro
Heterocycles 2008, 76, 329-351.

"Intramolecular Arylcyanation of Alkenes Catalyzed by Nickel/AlMe2Cl"
Nakao, Yoshiaki; Ebata, Shiro; Yada, Akira; Hiyama, Tamejiro; Ikawa, Masashi; Ogoshi, Sensuke
J. Am. Chem. Soc. 2008, 130, 12874-12875.

"Why Does Fluoride Anion Accelerate Transmetalation between Vinylsilane and Palladium(II)-Vinyl Complex? Theoretical Study"
Sugiyama, Akihiro; Ohnishi, Yu-ya; Nakaoka, Mayu; Nakao, Yoshihide; Sato, Hirofumi; Sakaki, Shigeyoshi; Nakao, Yoshiaki; Hiyama, Tamejiro
J. Am. Chem. Soc. 2008, 130, 12975-12985.

"Diels-Alder reaction of 2,3-bis(pinacolatoboryl)-1,3-butadiene: facile preparation of 1,2-bis(pinacolatoboryl)cyclohexenes and -1,4-cyclohexadiene"
Shimizu, Masaki; Shimono, Katsuhiro; Kurahashi, Takuya; Kiyomoto, Shin-ichi; Nagao, Ikuhiro; Hiyama, Tamejiro
Bull. Chem. Soc. Jpn. 2008, 81, 518-520.

"Solid state structures and photophysical properties of (trimethylsilyl)methyl-substituted anthracenes and pyrenes"
Shimizu, Masaki; Tatsumi, Hironori; Mochida, Kenji; Hiyama, Tamejiro
Chem. Commun. 2008, 2134-2136.

"Rhodium-catalyzed hydroarylation and hydroalkenylation of alkynes using organo[2-(hydroxymethyl)phenyl]dimethylsilanes"
Nakao, Yoshiaki; Takeda, Masahide; Chen, Jinshui; Hiyama, Tamejiro
Synlett 2008, 774-776.

"Rhodium-catalyzed addition of organo[2-(hydroxymethyl)phenyl]dimethylsilanes to arenesulfonylimines"
Nakao, Yoshiaki; Takeda, Masahide; Chen, Jinshui; Hiyama, Tamejiro; Ichikawa, Yoshitaka; Shintani, Ryo; Hayashi, Tamio
Chem. Lett. 2008, 37, 290-291.

"Multilayer holographic recording using a two-color-absorption photopolymer"
Hirabayashi, Katsuhiko; Kanbara, Hirohisa; Mori, Yuhei; Kurihara, Takashi; Shimizu, Masaki; Hiyama, Tamejiro
App. Optics 2007, 46, 8402-8410.

"A Strategy for C-H Activation of Pyridines: Direct C-2 Selective Alkenylation of Pyridines by Nickel/Lewis Acid Catalysis"
Nakao, Yoshiaki; Kanyiva, Kyalo Stephen; Hiyama, Tamejiro
J. Am. Chem. Soc. 2008, 130, 2448-2449.

"Nickel/BPh3-catalyzed alkynylcyanation of alkynes and 1,2-dienes: an efficient route to highly functionalized conjugated enynes"
Nakao, Yoshiaki; Hirata, Yasuhiro; Tanaka, Masaaki; Hiyama, Tamejiro
Angew. Chem. Int. Ed. 2008, 47, 385-387.

"One-Pot Syntheses of 2,3-Dihydrothiopyran-4-one Derivatives by Pd/Cu-Catalyzed Reactions of ,-Unsaturated Thioesters with Propargyl Alcohols"
Minami, Yasunori; Kuniyasu, Hitoshi; Kambe, Nobuaki
Org. Lett. 2008, 10, 2469-2472.


2007

"Nickel-catalyzed addition of pyridine-N-oxides across alkynes" Kanyiva, Kyalo Stephen; Nakao, Yoshiaki; Hiyama, Tamejiro
Angew. Chem. Int. Ed. 2007, 46, 8872-8874.

"Straightforward synthesis of CF3-substituted triarylethenes by stereoselective threefold cross-coupling reactions"
Takeda, Youhei; Shimizu, Masaki; Hiyama, Tamejiro
Angew. Chem. Int. Ed. 2007, 46, 8659-8661.

"Facile synthesis and palladium-catalyzed cross-coupling reactions of 2,3-bis(pinacolatoboryl)-1,3-butadiene" Shimizu, Masaki; Kurahashi, Takuya; Shimono, Katsuhiro; Tanaka, Kei; Nagao, Ikuhiro; Kiyomoto, Shin-ichi; Hiyama, Tamejiro
Chem.-Asian J. 2007, 2, 1400-1408.

"Catalytic Asymmetric Synthesis of Allylsilanes through Rhodium/Chiral Diene-Catalyzed 1,4-Addition of Alkenyl[2-(hydroxymethyl)phenyl]dimethylsilanes"
Shintani, Ryo; Ichikawa, Yoshitaka; Hayashi, Tamio; Chen, Jinshui; Nakao, Yoshiaki; Hiyama, Tamejiro
Org. Lett. 2007, 9, 4643-4645.

"Cascade triple-aldehyde addition of 1,2,3,4-tetrakis(pinacolatoboryl)but-2-ene: stereoselective synthesis of 2,3-bis(alkylidene)alkane-1,5-diols"
Shimizu, Masaki; Shimono, Katsuhiro; Hiyama, Tamejiro
Chem.-Asian J. 2007, 2, 1142-1149.

"Stereoselective cross-coupling reaction of 2,4-diaryl-1,1-diboryl-1,3-butadienes: stereocontrolled approach to 1,3,4,6-tetraarylated 1,3,5-hexatrienes"
Shimizu, Masaki; Shimono, Katsuhiro; Schelper, Michael; Hiyama, Tamejiro
Synlett 2007, 1969-1971.

"A Silicon-Based Approach to Oligoarenes by Iterative Cross-Coupling Reactions of Halogenated Organo[(2-hydroxymethyl)phenyl]dimethylsilanes"
Nakao, Yoshiaki; Chen, Jinshui; Tanaka, Masaaki; Hiyama, Tamejiro
J. Am. Chem. Soc. 2007, 129, 11694-11695.

"A novel strategy for two-photon holographic recording: stepwise two-photon absorption of -quinquethiophene followed by energy transfer to an aryl azide"
Shimizu, Masaki; Schelper, Michael; Mochida, Kenji; Hiyama, Tamejiro; Adachi, Masafumi; Sasaki, Yutaka; Akiyama, Seiji; Maeda, Shuuichi; Kanbara, Hirohisa; Mori, Yuhei; et al
Adv. Mater. 2007, 19, 1826-1829.

"Organo[2-(hydroxymethyl)phenyl]dimethylsilanes as Mild and Reproducible Agents for Rhodium-Catalyzed 1,4-Addition Reactions"
Nakao, Yoshiaki; Chen, Jinshui; Imanaka, Hidekazu; Hiyama, Tamejiro; Ichikawa, Yoshitaka; Duan, Wei-Liang; Shintani, Ryo; Hayashi, Tamio
J. Am. Chem. Soc. 2007, 129, 9137-9143.

"Cross-coupling reaction of allylic and benzylic carbonates with organo[2-(hydroxymethyl)phenyl]dimethylsilanes"
Nakao, Yoshiaki; Ebata, Shiro; Chen, Jinshui; Imanaka, Hidekazu; Hiyama, Tamejiro
Chem. Lett. 2007, 36, 606-607.

"Novel generation of 3,3,3-trifluoropropynyllithium and transformation of the carbonyl adducts to trifluoromethyl-substituted allenes"
Shimizu, Masaki; Higashi, Masahiro; Takeda, Youhei; Jiang, Guofang; Murai, Masahito; Hiyama, Tamejiro
Synlett 2007, 1163-1165.

"Practical approach for hydroheteroarylation of alkynes using bench-stable catalyst "
Kanyiva, Kyalo Stephen; Nakao, Yoshiaki; Hiyama, Tamejiro
Heterocycles 2007, 72, 677-680.

"1-Alkyl-2,3,5,6,7,8-hexasilabicyclo[2.2.2]octanes: unconventional class of mesomorphic columnar compounds "
Shimizu, Masaki; Nata, Masanori; Mochida, Kenji; Hiyama, Tamejiro; Ujiie, Seiji; Yoshio, Masafumi; Kato, Takashi
Angew. Chem. Int. Ed. 2007, 46, 3055-3058.

"Unique effects of 2,3,5,6,7,8-hexasilabicyclo[2.2.2]octan-1-yl moiety on photophysical properties of -conjugated system"
Shimizu, Masaki; Kawaguchi, Tomoaki; Oda, Katsunari; Hiyama, Tamejiro
Chem. Lett. 2007, 36, 412-413.

"A Dramatic Effect of Lewis-Acid Catalysts on Nickel-Catalyzed Carbocyanation of Alkynes "
Nakao, Yoshiaki; Yada, Akira; Ebata, Shiro; Hiyama, Tamejiro
J. Am. Chem. Soc. 2007, 129, 2428-2429.

"Synthesis and cross-coupling reaction of alkenyl[(2-hydroxymethyl)phenyl]dimethylsilanes "
Nakao, Yoshiaki; Imanaka, Hidekazu; Chen, Jinshui; Yada, Akira; Hiyama, Tamejiro
J. Organomet. Chem. 2007, 129, 585-603.

"1,1,3,3-Tetrakis(alkylthio)-1,3-dilithio-2-silapropanes: useful reagents for the synthesis of polysilacycloalkanes via dianionic ring formation "
Shimizu, Masaki; Iwakubo, Masayuki; Nishihara, Yasushi; Oda, Katsunari; Hiyama, Tamejiro
ARKIVOC 2007, 29-48.


2006

"Synthesis and applications of 1,1-diborylated cyclopropanes: facile route to 1,2-diboryl-3-methylenecyclopentenes "
Shimizu, Masaki; Schelper, Michael; Nagao, Ikuhiro; Shimono, Katsuhiro; Kurahashi, Takuya; Hiyama, Tamejiro
Chem. Lett. 2006, 35, 1222-1223.

Biaryl synthesis using highly stable aryl[2-(hydroxymethyl)phenyl]dimethylsilanes and aryl iodides under fluoride-free conditions "
Nakao, Yoshiaki; Sahoo, Akhila K.; Yada, Akira; Chen, Jinshui; Hiyama, Tamejiro
Sci. Technol. Adv. Mater. 2006, 7, 536-543.

"Preparation, structure, and properties of tris(trimethylsilyl)silyl-substituted anthracenes: realization of ideal conformation for - conjugation involving eclipse of Si-Si -bond with p-orbital of aromatic ring "
Shimizu, Masaki; Oda, Katsunari; Bando, Tomoaki; Hiyama, Tamejiro
Chem. Lett. 2006, 35, 1022-1023.

"(Z)-1,2,3,4-Tetraboryl-2-butene: a reagent for stereoselective one-pot triple aldehyde addition "
Shimizu, Masaki; Shimono, Katsuhiro; Hiyama, Tamejiro
Chem. Lett. 2006, 35, 838-839.

"Arylcyanation of norbornene and norbornadiene catalyzed by nickel "
Nakao, Yoshiaki; Yada, Akira; Satoh, Jun; Ebata, Shiro; Oda, Shinichi; Hiyama, Tamejiro
Chem. Lett. 2006, 35, 790-791.

"Arylcyanation of alkynes catalyzed by nickel "
Nakao, Yoshiaki; Oda, Shinichi; Yada, Akira; Hiyama, Tamejiro
Tetrahedron 2006, 62, 7567-7576.

"Hydroheteroarylation of Alkynes under Mild Nickel Catalysis "
Nakao, Yoshiaki; Kanyiva, Kyalo Stephen; Oda, Shinichi; Hiyama, Tamejiro
J. Am. Chem. Soc. 2006, 128, 8146-8147.

"Allylcyanation of Alkynes: Regio- and Stereoselective Access to Functionalized Di- or Trisubstituted Acrylonitriles "
Nakao, Yoshiaki; Yukawa, Tomoya; Hirata, Yasuhiro; Oda, Shinichi; Satoh, Jun; Hiyama, Tamejiro
J. Am. Chem. Soc. 2006, 128, 7116-7117.

"Cyanoesterification of 1,2-Dienes: Synthesis and Transformations of Highly Functionalized -Cyanomethylacrylate Esters"
Nakao, Yoshiaki; Hirata, Yasuhiro; Hiyama, Tamejiro
J. Am. Chem. Soc. 2006, 128, 7420-7421.

"Regio- and stereoselective decarbonylative carbostannylation of alkynes catalyzed by Pd/C "
Nakao, Yoshiaki; Satoh, Jun; Shirakawa, Eiji; Hiyama, Tamejiro
Angew. Chem. Int. Ed. 2006, 45, 2271-2274.

"Reactions of ,-Unsaturated Thioesters with Pt(0): Implication of Dual Mechanism Leading to the Formation of Acyl Platinum"
Minami, Yasunori; Kato, Tomohiro; Kuniyasu, Hitoshi; Terao, Jun; Kambe, Nobuaki
Organometallics 2006, 25, 2949-2959.

""-cis-SAr effect" on decarbonylation from ,-unsaturated acyl and aroyl complexes. "
Kato, Tomohiro; Kuniyasu, Hitoshi; Kajiura, Takamichi; Minami, Yasunori; Ohtaka, Atsushi; Kinomoto, Masanori; Terao, Jun; Kurosawa, Hideo; Kambe, Nobuaki
Chem. Commun. 2006, 868-869.


2005

"Facile synthesis of trifluoromethyl-substituted enynes: Remarkable reactivity and stereoselectivity of tributyl(3,3,3-trifluoropropynyl)stannane in carbostannylation of alkynes "
Shimizu, Masaki; Jiang, Guofang; Murai, Masahito; Takeda, Youhei; Nakao, Yoshiaki; Hiyama, Tamejiro; Shirakawa, Eiji
Chem. Lett. 2005, 34, 1700-1701.

"Stereospecific synthesis of hetero[7]helicenes by Pd-catalyzed double N-arylation and intramolecular O-arylation "
Nakano, Koji; Hidehira, Yuko; Takahashi, Keita; Hiyama, Tamejiro; Nozaki, Kyoko
Angew. Chem. Int. Ed. 2005, 44, 7136-7138.

"2,3,5,6,7,8-Hexasilabicyclo[2.2.2]octane-derived Columnar Liquid Crystals "
Shimizu, Masaki; Nata, Masanori; Watanabe, Kotaro; Hiyama, Tamejiro; Ujiie, Seiji
Mol. Cryst. Liq. Cryst. 2005, 441, 237-241.

"Stereoselective Cross-Coupling Reaction of 1,1-Diboryl-1-alkenes with Electrophiles: A Highly Stereocontrolled Approach to 1,1,2-Triaryl-1-alkenes "
Shimizu, Masaki; Nakamaki, Chihiro; Shimono, Katsuhiro; Schelper, Michael; Kurahashi, Takuya; Hiyama, Tamejiro
J. Am. Chem. Soc. 2005, 127, 12506-12507.

"Alkenyl- and Aryl[2-(hydroxymethyl)phenyl]dimethylsilanes: An Entry to Tetraorganosilicon Reagents for the Silicon-Based Cross-Coupling Reaction "
Nakao, Yoshiaki; Imanaka, Hidekazu; Sahoo, Akhila K.; Yada, Akira; Hiyama, Tamejiro
J. Am. Chem. Soc. 2005, 127, 6952-6953.

"Asymmetric amplification in asymmetric alternating copolymerization of cyclohexene oxide and carbon dioxide "
Nakano, Koji; Hiyama, Tamejiro; Nozaki, Kyoko
Chem. Commun. 2005, 1871-1873.